Nanostructuring versus microstructuring in battery electrodes
Battery electrodes comprise a mixture of active material particles, conductive carbon and
binder additives deposited onto a current collector. Although this basic design has persisted …
binder additives deposited onto a current collector. Although this basic design has persisted …
Ultimate limits to intercalation reactions for lithium batteries
MS Whittingham - Chemical reviews, 2014 - ACS Publications
There is a growing demand for energy storage, for intermittent renewable energy such as
solar and wind power, for transportation, and for the myriad portable electronic devices. By …
solar and wind power, for transportation, and for the myriad portable electronic devices. By …
Electrochemical ion insertion from the atomic to the device scale
Electrochemical ion insertion involves coupled ion–electron transfer reactions, transport of
guest species and redox of the host. The hosts are typically anisotropic solids with 2D …
guest species and redox of the host. The hosts are typically anisotropic solids with 2D …
A review on lithium-ion battery ageing mechanisms and estimations for automotive applications
Lithium-ion batteries have become the focus of research interest, thanks to their numerous
benefits for vehicle applications. One main limitation of these technologies resides in the …
benefits for vehicle applications. One main limitation of these technologies resides in the …
Nanomaterials for energy conversion and storage
Nanostructured materials are advantageous in offering huge surface to volume ratios,
favorable transport properties, altered physical properties, and confinement effects resulting …
favorable transport properties, altered physical properties, and confinement effects resulting …
Polyanionic (phosphates, silicates, sulfates) frameworks as electrode materials for rechargeable Li (or Na) batteries
C Masquelier, L Croguennec - Chemical Reviews, 2013 - ACS Publications
For more than 20 years, most of the technological achievements for the realization of
positive electrodes for practical rechargeable Li battery systems have been devoted to …
positive electrodes for practical rechargeable Li battery systems have been devoted to …
Nanoscale phenomena in lithium-ion batteries
The electrochemical properties and performances of lithium-ion batteries are primarily
governed by their constituent electrode materials, whose intrinsic thermodynamic and kinetic …
governed by their constituent electrode materials, whose intrinsic thermodynamic and kinetic …
Olivine LiFePO 4: the remaining challenges for future energy storage
Rechargeable batteries can effectively store electrical energy as chemical energy, and
release it when needed, providing a good choice for applications in electric vehicles (EVs) …
release it when needed, providing a good choice for applications in electric vehicles (EVs) …
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes
Introduction The ability to achieve high cycling rates in a lithium-ion battery is limited by the
Li transport within the electrolyte; the transport of Li ions and electrons within the electrodes; …
Li transport within the electrolyte; the transport of Li ions and electrons within the electrodes; …
Theory of chemical kinetics and charge transfer based on nonequilibrium thermodynamics
MZ Bazant - Accounts of chemical research, 2013 - ACS Publications
Advances in the fields of catalysis and electrochemical energy conversion often involve
nanoparticles, which can have kinetics surprisingly different from the bulk material. Classical …
nanoparticles, which can have kinetics surprisingly different from the bulk material. Classical …