Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …

Efficient hydrogen generation from aqueous protons through direct conversion of solar
energy is an essential prerequisite of a future hydrogen economy and easily accessible …

In this (tutorial overview) perspective we highlight the use of “redox non-innocent” ligands in
catalysis. Two main types of reactivity in which the redox non-innocent ligand is involved can …

Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

Mononuclear metalloenzymes in nature can function in cooperation with precisely
positioned redox-active organic cofactors in order to carry out multielectron catalysis …

This review discusses the use of multidentate actor ligands as new inroads to small
molecule activation and catalysis. Bio-inspired strategies such as the use of redox-active …

The first section provides a background to the whole review. The second presents a
historical perspective of fundamental developments in rhenium chemistry from its discovery …

The synthesis, spectroelectrochemical characterization (ultraviolet–visible and nuclear
magnetic resonance), solid state structures, and computational metric parameters of three …

Conspectus Homogeneous catalysis is at the forefront of global efforts to innovate the
synthesis of fine chemicals and achieve carbon-neutrality in energy applications. For …

The construction of C–S bonds is of great importance in the field of synthetic and medicinal
chemistry. Herein, solvent-induced umpolung reactions from dioxygenation to interligand C …