Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers
P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
Electronic structure modeling of metal–organic frameworks
Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …
Intermolecular interaction characteristics of the all-carboatomic ring, cyclo [18] carbon: Focusing on molecular adsorption and stacking
Z Liu, T Lu, Q Chen - Carbon, 2021 - Elsevier
Recently, an intriguing all-carboatomic ring, cyclo [18] carbon, was observed in the
condensed phase for the first time, and it quickly attracted widespread attention. In this …
condensed phase for the first time, and it quickly attracted widespread attention. In this …
In-depth study of heavy metal removal by an etidronic acid-functionalized layered double hydroxide
Sorption methodologies play a pivotal role in heavy metal removal to meet the global
requirements for uninterrupted access to drinkable water. Standard sorption technologies …
requirements for uninterrupted access to drinkable water. Standard sorption technologies …
14.7% efficiency organic photovoltaic cells enabled by active materials with a large electrostatic potential difference
Although significant improvements have been achieved for organic photovoltaic cells
(OPVs), the top-performing devices still show power conversion efficiencies far behind those …
(OPVs), the top-performing devices still show power conversion efficiencies far behind those …
The halogen bond
The halogen bond occurs when there is evidence of a net attractive interaction between an
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
Halogen bonding in supramolecular chemistry
LC Gilday, SW Robinson, TA Barendt… - Chemical …, 2015 - ACS Publications
Supramolecular chemistry is “the chemistry of the intermolecular bond, covering the
structures and functions of the entities formed by association of two or more chemical …
structures and functions of the entities formed by association of two or more chemical …
Single layer graphene encapsulating non-precious metals as high-performance electrocatalysts for water oxidation
The oxygen evolution reaction (OER) is recognized as a key half-reaction in water
electrolysis for clean hydrogen energy, which is kinetically not favored and usually requires …
electrolysis for clean hydrogen energy, which is kinetically not favored and usually requires …
The σ-hole revisited
P Politzer, JS Murray, T Clark, G Resnati - … Chemistry Chemical Physics, 2017 - pubs.rsc.org
A covalently-bonded atom typically has a region of lower electronic density, a “σ-hole,” on
the side of the atom opposite to the bond, along its extension. There is frequently a positive …
the side of the atom opposite to the bond, along its extension. There is frequently a positive …
Computer modeling of halogen bonds and other σ-hole interactions
MH Kolar, P Hobza - Chemical reviews, 2016 - ACS Publications
In the field of noncovalent interactions a new paradigm has recently become popular. It
stems from the analysis of molecular electrostatic potentials and introduces a label, which …
stems from the analysis of molecular electrostatic potentials and introduces a label, which …