The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …

Alkene functionalisation is a powerful strategy that has enabled access to a wide array of
compounds including valuable pharmaceuticals and agrochemicals. The reactivity of the …

Dipolar aprotic and ethereal solvents comprise just over 40% of all organic solvents utilized
in synthetic organic, medicinal, and process chemistry. Unfortunately, many of the common …

Metal-catalyzed highly Markovnikov-type selective hydrofunctionalization of terminal alkynes
provides a straightforward and atom-economical route to access 1, 1-disubstituted alkenes …

An intermolecular, photocatalytic dicarbofunctionalization (DCF) of olefins enabled by the
merger of Giese-type addition with Ni/photoredox dual catalysis has been realized …

The incorporation of alkenylboronates into axially chiral compounds increases their
structural diversity and provides a synthetic handle for late-stage functionalizations. Despite …

The enantioconvergent radical C (sp3)–C (sp2) cross-coupling of alkyl halides with
alkenylboronate esters is an appealing tool in the assembly of synthetically valuable …

The condensation of easy manageable lithium α-bis (boryl) carbanions with carbonyl
derivatives, the so-called boron-Wittig reaction, allows for the straightforward and often …