Hierarchical self-assembly of ABC-type bottlebrush copolymers

Q Song, Q Dong, R Liang, Y Xue, M Zhong… - Macromolecules, 2023 - ACS Publications
We have performed dissipative particle dynamics simulations to study the self-assembly of
ABC-type bottlebrush copolymers (BBCPs), one portion of whose backbone is grafted by …

Coarse-grained, implicit side-chain model of bottlebrush polymer melts

H Kang, T Pan, CE Sing - Macromolecules, 2024 - ACS Publications
The unique architecture of bottlebrush polymers gives rise to multiple molecular parameters
consisting of the bottlebrush backbone length (N bb), side chain length (N sc), and grafting …

Assessment of the partial saddle point approximation in field-theoretic polymer simulations

T Quah, KT Delaney, GH Fredrickson - The Journal of Chemical …, 2023 - pubs.aip.org
Field-theoretic simulations are numerical treatments of polymer field theory models that go
beyond the mean-field self-consistent field theory level and have successfully captured a …

Architectural Design of Block Copolymers

Z Xu, Q Dong, W Li - Macromolecules, 2024 - ACS Publications
Highly designable architectures of polymers endow the same polymer with different
properties. In principle, diverse architectures should enrich the self-assembly behavior of …

Phase Behavior and Conformational Asymmetry near the Comb-to-Bottlebrush Transition in Linear-Brush Block Copolymers

RJ Sánchez-Leija, JA Mysona, JJ de Pablo… - …, 2024 - ACS Publications
This study explores how conformational asymmetry influences the bulk phase behavior of
linear-brush block copolymers. We synthesized 60 diblock copolymers composed of poly …

Exploring conformations of comb-like polymers with varying grafting density in dilute solutions

CA Salinas-Soto, Y Choe, SM Hur… - The Journal of …, 2023 - pubs.aip.org
Comb-like polymers have shown potential as advanced materials for a diverse palette of
applications due to the tunability of their polymer architecture. To date, however, it still …

Phase Behavior of Linear-Star Topology-Transformable Block Copolymers

S Zhao, J Yu, Z Liu, J Zhang, Y Yan, Q Dong… - …, 2024 - ACS Publications
Linear-star topology-transformable copolymers are a new class of block copolymers
employing freely sliding rotaxane structures instead of covalent bonds to connect different …