Covering: 2015 to 2020 The ent-kaurane diterpenoids are integral parts of tetracyclic natural
products that are widely distributed in terrestrial plants. These compounds have been found …

Conspectus Polycyclic natural products are an inexhaustible source of medicinal agents,
and their complex molecular architecture renders challenging synthetic targets where …

We have accomplished the total synthesis of sculponin U, a polycyclic C‐20‐oxygenated
kaurane diterpenoid featuring a 7, 20‐lactone‐hemiketal bridge, through a radical cascade …

Herein, we present a photocatalyzed two‐carbon ring expansion of β‐dicarbonyl
compounds with unactivated olefins that provides facile access to medium‐sized rings …

A unified strategy toward asymmetric divergent syntheses of nine C8-ethano-bridged
diterpenoids A1–A9 (candol A, powerol, sicanadiol, epi-candol A, atisirene, ent-atisan-16α …

Catalytic asymmetric de Mayo reaction was achieved for the first time under visible light
using asymmetric binary acid catalysis (ABC) involving zirconium chloride and chiral …

Abstract In 1962, Paul J. de Mayo initially described the photochemical reaction involving 1,
3‐diketones and double bonds, resulting in the formation of 1, 5‐diketones. Since then, this …

The divergent synthesis of natural products is rapidly developing towards achieving the goal
of efficiency and economy in total synthesis. However, presently, the sustainable …

Platensilin, platensimycin, and platencin are potent inhibitors of β-ketoacyl–acyl carrier
protein synthase (FabF) in the bacterial and mammalian fatty acid synthesis system …

Visible-light promoted de Mayo reaction by zirconium catalysis - Chemical Communications
(RSC Publishing) DOI:10.1039/D2CC05029C Royal Society of Chemistry View PDF VersionPrevious …