Coordination-induced bond weakening is a phenomenon wherein ligand X–H bond
homolysis occurs in concert with the energetically favorable oxidation of a coordinating …

Proton transfer reactions involving transition metal hydride complexes are prevalent in a
number of catalytic fuel-forming reactions, where the proton transfer kinetics to or from the …

Coordination of alcohols to the single-electron reductant samarium diiodide (SmI2) results in
substantial O–H bond weakening, affording potent proton-coupled electron transfer (PCET) …

Phosphorus mononitride (PN) only has a fleeting existence on Earth, and molecular
precursors for the release of this molecule under mild conditions in solution have remained …

Protonation reactions involving organometallic complexes are ubiquitous in redox chemistry
and often result in the generation of reactive metal hydrides. However, some organometallic …

The cyclopentadienyl (Cp) ligand is a cornerstone of modern organometallic chemistry.
Since the discovery of ferrocene, the Cp ligand and its various derivatives have become …

Cyclopentadienyl (Cp), a classic ancillary ligand platform, can be chemically noninnocent in
electrocatalytic H–H bond formation reactions via protonation of coordinated η5-Cp ligands …

Two-electron, one-proton reactions of a family of [CoCp (dxpe)(NCCH3)] 2+ complexes (Cp=
cyclopentadienyl, dxpe= 1, 2-bis (di (aryl/alkyl) phosphino) ethane) form the corresponding …

The synthesis of a piano-stool ruthenium hydride,[(η5-C5Me5) Ru (PmIm) H](PmIm=(N-(1, 3,
5-trimethylphenyl)-1-(pyrimidin-2-yl) ethan-1-imine), for the dual purpose of catalytic …

Transition metal-catalyzed reversible hydrogenation of CO2 to formate in aqueous solutions
under ambient conditions is an attractive environmentally friendly strategy for the storage …