Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
Single-atom alloy catalysis
RT Hannagan, G Giannakakis… - Chemical …, 2020 - ACS Publications
Single-atom alloys (SAAs) play an increasingly significant role in the field of single-site
catalysis and are typically composed of catalytically active elements atomically dispersed in …
catalysis and are typically composed of catalytically active elements atomically dispersed in …
Guidelines to achieving high selectivity for the hydrogenation of α, β-unsaturated aldehydes with bimetallic and dilute alloy catalysts: a review
Selective hydrogenation of α, β-unsaturated aldehydes to unsaturated alcohols is a
challenging class of reactions, yielding valuable intermediates for the production of …
challenging class of reactions, yielding valuable intermediates for the production of …
Dilute alloys based on Au, Ag, or Cu for efficient catalysis: from synthesis to active sites
The development of new catalyst materials for energy-efficient chemical synthesis is critical
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …
Fundamental aspects of alkyne semi-hydrogenation over heterogeneous catalysts
Z Wang, Q Luo, S Mao, C Wang, J Xiong, Z Chen… - Nano Research, 2022 - Springer
Alkyne semi-hydrogenation is extremely significant for the production of polymer-grade
ethylene and lots of fine chemicals in modern industry. Many efforts had been devoted to …
ethylene and lots of fine chemicals in modern industry. Many efforts had been devoted to …
Decoding reactive structures in dilute alloy catalysts
Rational catalyst design is crucial toward achieving more energy-efficient and sustainable
catalytic processes. Understanding and modeling catalytic reaction pathways and kinetics …
catalytic processes. Understanding and modeling catalytic reaction pathways and kinetics …
Evaporation-induced self-assembly of metal oxide inverse opals: From synthesis to applications
Conspectus Inverse opals (IOs) are highly interconnected three-dimensional macroporous
structures with applications in a variety of disciplines from optics to catalysis. For instance …
structures with applications in a variety of disciplines from optics to catalysis. For instance …
Tuning the Hydrogenation Selectivity of an Unsaturated Aldehyde via Single-Atom Alloy Catalysts
Selective hydrogenation of α, β-unsaturated aldehydes to produce unsaturated alcohols
remains a challenge in catalysis. Here, we explore, on the basis of first-principles …
remains a challenge in catalysis. Here, we explore, on the basis of first-principles …
Dynamic modification of palladium catalysts with chain alkylamines for the selective hydrogenation of alkynes
Q Luo, Z Wang, Y Chen, S Mao, K Wu… - … Applied Materials & …, 2021 - ACS Publications
Selective hydrogenation of alkynes plays a pivotal role in the field of chemical production but
still suffers from restrained catalytic activity and low alkene selectivity. Herein, a dynamic …
still suffers from restrained catalytic activity and low alkene selectivity. Herein, a dynamic …
Dynamical study of adsorbate-induced restructuring kinetics in bimetallic catalysts using the PdAu (111) model system
Dynamic restructuring of bimetallic catalysts plays a crucial role in their catalytic activity and
selectivity. In particular, catalyst pretreatment with species such as carbon monoxide and …
selectivity. In particular, catalyst pretreatment with species such as carbon monoxide and …