In this paper first a generally valid model is derived from the two fundamental equations of
Gibbs for temperature and composition dependences of all types of interfacial energies. This …

The abbreviation “nano-Calphad” stands for “Calculation of Phase Diagrams for nano-
systems.” Nano-systems contain at least one phase or at least one interface layer (film …

The general equation is derived for the equilibrium of a small solid particle and a large
solution, being consistent with the thermodynamics of Gibbs. This equation can be solved in …

The purpose of this article is to give a set of recommendations to producers of assessed
thermodynamic data, who may be involved in either the critical evaluation of limited …

The rule of Lupis and Elliott (LE rule) proposed for the first time in 1966 is reformulated in
this article as,“Real solid, liquid and gaseous solutions (and pure gases) gradually approach …

Based on the data of the literature reports, the Al–Zr binary system has been re-assessed
thermodynamically through the CALPHAD (CALculations of PHAse Diagram) approach …

An exponential formulation was proposed to replace the linear interaction parameter in the
Redlich–Kister (R–K) polynomial for the excess Gibbs energy of ternary solution phase. The …

The Butler equation is extended to model equilibrium grain boundary (GB) energy and the
equilibrium GB composition of a polycrystal, as a function of the following state parameters …

The exponential model for the temperature (T) dependence of the excess Gibbs energy of
liquid solutions within the framework of the Redlich-Kister polynomials is proven to be an …

This paper is part of a series of studies on the development of a multi-temperature
thermodynamically consistent model for salt lake brine systems. The objective of this study is …