Magnetic criteria of aromaticity
R Gershoni-Poranne, A Stanger - Chemical Society Reviews, 2015 - pubs.rsc.org
This review describes the current state of magnetic criteria of aromaticity. The introduction
contains the fundamentals of ring currents in aromatic and antiaromatic systems, followed by …
contains the fundamentals of ring currents in aromatic and antiaromatic systems, followed by …
Charge makes a difference: molecular ionic bismuth compounds
J Heine, B Peerless, S Dehnen… - Angewandte Chemie …, 2023 - Wiley Online Library
Key challenges in modern synthetic chemistry include the design of reliable, selective, and
more sustainable synthetic methods, as well as the development of promising candidates for …
more sustainable synthetic methods, as well as the development of promising candidates for …
Highly Strained Arene-Fused 1, 2-Diborete Biradicaloid
A Gärtner, L Meier, M Arrowsmith… - Journal of the …, 2022 - ACS Publications
The stepwise reduction of a doubly cyclic alkyl (amino) carbene (CAAC)-stabilized 2, 3-bis
(dibromoboryl) naphthalene enables the isolation of the corresponding mono-and bis (boryl) …
(dibromoboryl) naphthalene enables the isolation of the corresponding mono-and bis (boryl) …
Aromaticity, the Hückel 4 n+ 2 rule and magnetic current
L Zhao, R Grande‐Aztatzi, C Foroutan‐Nejad… - …, 2017 - Wiley Online Library
Quantum chemical calculations using density functional theory and correlated ab initio
methods of the 10 π‐electron systems (N6H6) 2+ and C2N4H6 show that the planar forms …
methods of the 10 π‐electron systems (N6H6) 2+ and C2N4H6 show that the planar forms …
A critical assessment of the performance of magnetic and electronic indices of aromaticity
The lack of reference aromatic systems in the realm of inorganic aromatic compounds
makes the evaluation of aromaticity in all-metal and semimetal clusters a difficult task. To …
makes the evaluation of aromaticity in all-metal and semimetal clusters a difficult task. To …
Integration of global ring currents using the Ampère–Maxwell law
RJF Berger, M Dimitrova, RT Nasibullin… - Physical Chemistry …, 2022 - pubs.rsc.org
Magnetically induced ring currents are calculated from the magnetic shielding tensor by
employing the Ampère–Maxwell law. The feasibility of the method is demonstrated by …
employing the Ampère–Maxwell law. The feasibility of the method is demonstrated by …
All‐Metal Antiaromaticity in Sb4‐Type Lanthanocene Anions
Antiaromaticity, as introduced in 1965, usually refers to monocyclic systems with 4n π
electrons. This concept was extended to all‐metal molecules after the observation of Li3Al4 …
electrons. This concept was extended to all‐metal molecules after the observation of Li3Al4 …
Dibenzoberylloles: antiaromatic s-block fluorene analogues
T Tröster, F Endres, M Arrowsmith, L Endres… - Chemical …, 2023 - pubs.rsc.org
Among a series of Lewis-base-stabilised antiaromatic dibenzoberylloles (DBBes) the cyclic
alkyl (amino) carbene (CAAC) analogue undergoes a complex but highly selective thermal …
alkyl (amino) carbene (CAAC) analogue undergoes a complex but highly selective thermal …
A test to evaluate the performance of aromaticity descriptors in all-metal and semimetal clusters. An appraisal of electronic and magnetic indicators of aromaticity
As compared to classical organic aromatic compounds, the evaluation of aromaticity in all-
metal and semimetal clusters is much more complex. For a series of these clusters, it is …
metal and semimetal clusters is much more complex. For a series of these clusters, it is …
Boroles from alumoles: accessing boroles with alkyl-substituted backbones via transtrielation
JL Bohlen, L Endres, R Drescher, K Radacki… - Chemical …, 2023 - pubs.rsc.org
The alumole Cp3tAlC4Et4 (Cp3t= 1, 2, 4-tris (tert-butyl) cyclopentadienyl) is reported to be
capable of transferring its butadiene moiety to aryl (dihalo) boranes to generate boroles …
capable of transferring its butadiene moiety to aryl (dihalo) boranes to generate boroles …