Chiral metal–organic frameworks

W Gong, Z Chen, J Dong, Y Liu, Y Cui - Chemical Reviews, 2022 - ACS Publications
In the past two decades, metal–organic frameworks (MOFs) or porous coordination polymers
(PCPs) assembled from metal ions or clusters and organic linkers via metal–ligand …

Critical Aspects and Recent Advances in Structural Engineering of Photocatalysts for Sunlight‐Driven Photocatalytic Reduction of CO2 into Fuels

NN Vu, S Kaliaguine, TO Do - Advanced Functional Materials, 2019 - Wiley Online Library
The catalytic conversion of CO2 into valuable fuels is a compelling solution for tackling the
global warming and fuel crisis. Light absorption and charge separation, as well as …

Atomically dispersed metal sites in MOF‐based materials for electrocatalytic and photocatalytic energy conversion

Z Liang, C Qu, D Xia, R Zou… - Angewandte Chemie …, 2018 - Wiley Online Library
Metal sites play an essential role in both electrocatalytic and photocatalytic energy
conversion. The highly ordered arrangements of the organic linkers and metal nodes as well …

Best practices for the synthesis, activation, and characterization of metal–organic frameworks

AJ Howarth, AW Peters, NA Vermeulen… - Chemistry of …, 2017 - ACS Publications
Metal–organic frameworks (MOFs) are structurally diverse materials comprised of inorganic
and organic components. As the rapidly expanding field of MOF research has demonstrated …

Asymmetric catalysis using metal-organic frameworks

DN Dybtsev, KP Bryliakov - Coordination Chemistry Reviews, 2021 - Elsevier
To date, porous coordination polymers (metal–organic frameworks, MOFs) have been
extensively studied in multiple applications, including the use of homohiral or chirally …

MOF catalysis in relation to their homogeneous counterparts and conventional solid catalysts

P García-García, M Müller, A Corma - Chemical Science, 2014 - pubs.rsc.org
Metal–organic frameworks have recently attracted attention as heterogeneous catalysts due
to their high content of metal centres and large surface area and pore volume, along with …

Privileged phosphine-based metal–organic frameworks for broad-scope asymmetric catalysis

JM Falkowski, T Sawano, T Zhang, G Tsun… - Journal of the …, 2014 - ACS Publications
A robust and porous Zr metal–organic framework (MOF) based on a BINAP-derived
dicarboxylate linker, BINAP-MOF, was synthesized and post-synthetically metalated with Ru …

Metal–organic framework (MOF)-based nanomaterials for biomedical applications

Z Luo, S Fan, C Gu, W Liu, J Chen… - Current medicinal …, 2019 - ingentaconnect.com
Background: Metal-organic frameworks (MOFs), as a new class of porous organic-inorganic
crystalline hybrid materials that governed by the self-assembled of metal atoms and organic …

NiO-PTA supported on ZIF-8 as a highly effective catalyst for hydrocracking of Jatropha oil

J Liu, J He, L Wang, R Li, P Chen, X Rao, L Deng… - Scientific reports, 2016 - nature.com
Nickel oxide (NiO) and phosphotungstic acid (PTA) supported on a ZIF-8 (NiO-PTA/ZIF-8)
catalyst was first synthesized and it showed high activity and good selectivity for the …

Robust and porous β-diketiminate-functionalized metal–organic frameworks for earth-abundant-metal-catalyzed C–H amination and hydrogenation

NC Thacker, Z Lin, T Zhang, JC Gilhula… - Journal of the …, 2016 - ACS Publications
We have designed a strategy for postsynthesis installation of the β-diketiminate (NacNac)
functionality in a metal–organic framework (MOF) of UiO-topology. Metalation of the NacNac …