Biochar Meets Single‐Atom: A Catalyst for Efficient Utilization in Environmental Protection Applications and Energy Conversion

T Zhou, J Deng, Y Zeng, X Liu, B Song, S Ye, M Li… - Small, 2024 - Wiley Online Library
Abstract Single‐atom catalysts (SACs), combining the advantages of multiphase and
homogeneous catalysis, have been increasingly investigated in various catalytic …

High-speed imaging and quantitative analysis of nonequilibrium stochastic processes using atomic resolution electron microscopy

T Nakamuro - Bulletin of the Chemical Society of Japan, 2024 - academic.oup.com
Chemical phenomena are inherently complex and stochastic, making them difficult to fully
understand using conventional ensemble-averaged analytical methods. These methods …

Highly Efficient Iridium–Iron–Molybdenum Catalysts Condensed on Boron Nitride for Biomass-Derived Diols' Hydrogenolysis to Secondary Monoalcohols

B Liu, Y Nakagawa, M Yabushita… - Journal of the American …, 2024 - ACS Publications
A trade-off of activity–selectivity exists in primary C–O hydrogenolysis of biomass-derived
diols to secondary alcohols over bimetallic catalysts, especially the combination of noble …

Rapid Polyolefin Plastic Hydrogenolysis Mediated by Single-Site Heterogeneous Electrophilic/Cationic Organo-group IV Catalysts

WC Edenfield, AH Mason, Q Lai, A Agarwal… - ACS …, 2023 - ACS Publications
A homologous series of cationic electrophilic group IV metal hydrides (M= Ti, Zr, Hf) created
by chemisorption of the corresponding MNp4 precursors on highly Brønsted acidic sulfated …

An active, stable cubic molybdenum carbide catalyst for the high-temperature reverse water-gas shift reaction

M Ahmadi Khoshooei, X Wang, G Vitale, F Formalik… - Science, 2024 - science.org
Although technologically promising, the reduction of carbon dioxide (CO2) to produce
carbon monoxide (CO) remains economically challenging owing to the lack of an …

Demystifying group-4 polyolefin hydrogenolysis catalysis: Gaseous propane hydrogenolysis mechanism over the same catalysts

AH Mason, A Motta, Y Kratish, TJ Marks - Proceedings of the National …, 2024 - pnas.org
A kinetic/mechanistic investigation of gaseous propane hydrogenolysis over the single-site
heterogeneous polyolefin depolymerization catalysts AlS/ZrNp2 and AlS/HfNp2 (AlS …

Molybdenum-doped carbon nitride as an efficient heterogeneous catalyst for direct amination of nitroarenes with arylboronic acids

WJ Li, JB Wang, YH Liu, M Zhang, ZH Zhang - Chinese Chemical Letters, 2024 - Elsevier
Heterogeneous metal-catalyzed chemical conversions with a recyclable catalyst are very
ideal and challenging for sustainable organic synthesis. A new bipyridyl-Mo (IV)-carbon …

Aldehyde and Ketone Hydroboration Mediated by a Heterogeneous Single‐Site Molybdenum‐Dioxo Catalyst: Scope and Mechanistic Implications

Y Liu, A Agarwal, L Ye, Y Kratish, TJ Marks - ChemCatChem, 2024 - Wiley Online Library
Efficient hydroboration of aldehydes and ketones is demonstrated using a single‐site MoO2
catalyst supported on activated carbon. Under mild conditions with low catalytic loadings …

Models for Single‐Site Heterogeneous Catalysts on Carbon: MoO2 Epoxidation Catalyst Anchored to a Fullerene

A Agarwal, Y Liu, OA Kraevaya, S Alayoglu… - …, 2024 - Wiley Online Library
Single‐site molybdenum dioxo catalysts, fullerenol/MoO2, are prepared via grafting
precursor (DME) MoO2Cl2 onto a highly polyhydroxylated fullerene (ful) and an isomerically …

Waste‐Derived Catalyst for Biodiesel Manufacturing in CO2‐Free Manner: Preparation, Catalytic Activity and Reuse Studies

AN Potorochenko, YV Gyrdymova, K Rodygin - ChemCatChem - Wiley Online Library
Currently, CaO‐based catalysts for biodiesel manufacturing are produced by calcination of
available limestone ore consisting of CaCO3. The production of 1 ton of CaO catalyst …