Oxygen Evolution/Reduction Reaction Catalysts: From In Situ Monitoring and Reaction Mechanisms to Rational Design

Y Zhao, DP Adiyeri Saseendran, C Huang… - Chemical …, 2023 - ACS Publications
The oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are core steps of
various energy conversion and storage systems. However, their sluggish reaction kinetics …

Water oxidation catalysts for artificial photosynthesis

S Ye, C Ding, M Liu, A Wang, Q Huang… - Advanced …, 2019 - Wiley Online Library
Water oxidation is the primary reaction of both natural and artificial photosynthesis.
Developing active and robust water oxidation catalysts (WOCs) is the key to constructing …

Molecular and heterogeneous water oxidation catalysts: recent progress and joint perspectives

J Li, CA Triana, W Wan, DPA Saseendran… - Chemical Society …, 2021 - pubs.rsc.org
The development of reliable water oxidation catalysts (WOCs) is essential for implementing
artificial photosynthesis on a large technological scale. WOC research has evolved into two …

Bioinspired and bioderived aqueous electrocatalysis

J Barrio, A Pedersen, S Favero, H Luo, M Wang… - Chemical …, 2022 - ACS Publications
The development of efficient and sustainable electrochemical systems able to provide clean-
energy fuels and chemicals is one of the main current challenges of materials science and …

Photochemistry journey to multielectron and multiproton chemical transformation

SL Meng, C Ye, XB Li, CH Tung… - Journal of the American …, 2022 - ACS Publications
The odyssey of photochemistry is accompanied by the journey to manipulate “electrons” and
“protons” in time, in space, and in energy. Over the past decades, single-electron (1e–) …

Bioinspired Trinuclear Copper Catalyst for Water Oxidation with a Turnover Frequency up to 20000 s–1

QF Chen, ZY Cheng, RZ Liao… - Journal of the American …, 2021 - ACS Publications
Solar-powered water splitting is a dream reaction for constructing an artificial photosynthetic
system for producing solar fuels. Natural photosystem II is a prototype template for research …

Heterobimetallic NiFe cooperative molecular water oxidation catalyst

HT Zhang, YH Guo, Y Xiao, HY Du… - Angewandte Chemie …, 2023 - Wiley Online Library
We reported herein the development of heterobimetallic NiFe molecular platform to
understand NiFe synergistic effect in water oxidation catalysis. Compared to homonuclear …

Molecular engineering of a 3D self‐supported electrode for oxygen electrocatalysis in neutral media

L Xie, X Li, B Wang, J Meng, H Lei… - Angewandte Chemie …, 2019 - Wiley Online Library
Electrodes for oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are
required in energy conversion and storage technologies. An assembly strategy involves …

Constructing Co4(SO4)4 Clusters within Metal–Organic Frameworks for Efficient Oxygen Electrocatalysis

Z Liang, G Zhou, H Tan, Y Mou, J Zhang… - Advanced …, 2024 - Wiley Online Library
Multinuclear metal clusters are ideal candidates to catalyze small molecule activation
reactions involving the transfer of multiple electrons. However, synthesizing active metal …

Identifying metal-oxo/peroxo intermediates in catalytic water oxidation by in situ electrochemical mass spectrometry

X Zhang, QF Chen, J Deng, X Xu, J Zhan… - Journal of the …, 2022 - ACS Publications
Molecular catalysis of water oxidation has been intensively investigated, but its mechanism
is still not yet fully understood. This study aims at capturing and identifying key short-lived …