This Perspective illustrates the defining characteristics of free radical chemistry, beginning
with its rich and storied history. Studies from our laboratory are discussed along with recent …

The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Azines, which are six-membered aromatic compounds containing one or more nitrogen
atoms, serve as ubiquitous structural cores of aromatic species with important applications in …

Carbon–carbon/carbon–heteroatom bond formation via oxidative transformations is a
heavily explored topic at the frontier of chemistry. Potassium persulfate (K2S2O8) has …

Quinoxaline has become a subject of extensive research due to its emergence as an
important chemical moiety, demonstrating a wide range of physicochemical and biological …

Potassium persulfate‐mediated thiocyanation of 2H‐indazoles has been developed using
ammonium thiocyanate as thiocyanating agent under iron‐catalysis at room temperature. 2 …

The first iron-catalysed enantioselective Suzuki–Miyaura coupling reaction has been
developed. In the presence of catalytic amounts of FeCl2 and (R, R)-QuinoxP*, lithium …

Pyridine rings are ubiquitous in drug molecules; however, the pre-eminent reaction used to
form carbon–carbon bonds in the pharmaceutical industry, the Suzuki–Miyaura cross …

A simple generation method of carbon radicals via 1e-oxidation of organotrifluoroborates
and carboxylic acids by the action of an organophotoredox catalyst, 9-mesityl-10 …

A novel ligand-free, transition metal-free direct C–H functionalization of quinones with
diaryliodonium salts has been developed for the first time. The transformation was promoted …