The ultrafast X-ray spectroscopic revolution in chemical dynamics

PM Kraus, M Zürch, SK Cushing, DM Neumark… - Nature Reviews …, 2018 - nature.com
The past two decades have seen rapid developments in short-pulse X-ray sources, which
have enabled the study of nuclear and electronic dynamics by ultrafast X-ray spectroscopies …

Short-wavelength free-electron laser sources and science: a review

EA Seddon, JA Clarke, DJ Dunning… - Reports on Progress …, 2017 - iopscience.iop.org
This review is focused on free-electron lasers (FELs) in the hard to soft x-ray regime. The
aim is to provide newcomers to the area with insights into: the basic physics of FELs, the …

Real-time observation of internal motion within ultrafast dissipative optical soliton molecules

K Krupa, K Nithyanandan, U Andral, P Tchofo-Dinda… - Physical review …, 2017 - APS
Real-time access to the internal ultrafast dynamics of complex dissipative optical systems
opens new explorations of pulse-pulse interactions and dynamic patterns. We present the …

Roadmap of ultrafast x-ray atomic and molecular physics

L Young, K Ueda, M Gühr… - Journal of Physics B …, 2018 - iopscience.iop.org
X-ray free-electron lasers (XFELs) and table-top sources of x-rays based upon high
harmonic generation (HHG) have revolutionized the field of ultrafast x-ray atomic and …

Imaging CF3I conical intersection and photodissociation dynamics with ultrafast electron diffraction

J Yang, X Zhu, TJA Wolf, Z Li, JPF Nunes, R Coffee… - Science, 2018 - science.org
Conical intersections play a critical role in excited-state dynamics of polyatomic molecules
because they govern the reaction pathways of many nonadiabatic processes. However …

Coherent structural trapping through wave packet dispersion during photoinduced spin state switching

HT Lemke, KS Kjær, R Hartsock, TB Van Driel… - Nature …, 2017 - nature.com
The description of ultrafast nonadiabatic chemical dynamics during molecular photo-
transformations remains challenging because electronic and nuclear configurations impact …

Diffractive imaging of coherent nuclear motion in isolated molecules

J Yang, M Guehr, X Shen, R Li, T Vecchione, R Coffee… - Physical review …, 2016 - APS
Observing the motion of the nuclear wave packets during a molecular reaction, in both
space and time, is crucial for understanding and controlling the outcome of photoinduced …

Ultrafast X-ray scattering reveals vibrational coherence following Rydberg excitation

B Stankus, H Yong, N Zotev, JM Ruddock… - Nature …, 2019 - nature.com
The coherence and dephasing of vibrational motions of molecules constitute an integral part
of chemical dynamics, influence material properties and underpin schemes to control …

Mapping the emergence of molecular vibrations mediating bond formation

JG Kim, S Nozawa, H Kim, EH Choi, T Sato, TW Kim… - Nature, 2020 - nature.com
Fundamental studies of chemical reactions often consider the molecular dynamics along a
reaction coordinate using a calculated or suggested potential energy surface,,,–. But fully …

Imaging conical intersection dynamics during azobenzene photoisomerization by ultrafast X-ray diffraction

D Keefer, F Aleotti, JR Rouxel… - Proceedings of the …, 2021 - National Acad Sciences
X-ray diffraction is routinely used for structure determination of stationary molecular samples.
Modern X-ray photon sources, eg, from free-electron lasers, enable us to add temporal …