Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Advances in the synthesis of preceramic polymers for the formation of silicon-based and ultrahigh-temperature non-oxide ceramics
Preceramic polymers (PCPs) are a group of specialty macromolecules that serve as
precursors for generating inorganics, including ceramic carbides, nitrides, and borides …
precursors for generating inorganics, including ceramic carbides, nitrides, and borides …
Nickel hydride complexes
NA Eberhardt, H Guan - Chemical reviews, 2016 - ACS Publications
Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
Reactions of hydrosilanes with transition metal complexes
JY Corey - Chemical Reviews, 2016 - ACS Publications
This third review in a series involving reactions of hydrosilanes and transition metal
complexes and characterization of the products covers the period 2009 thru 2013. After a …
complexes and characterization of the products covers the period 2009 thru 2013. After a …
Complexes of Ni (I): a “rare” oxidation state of growing importance
Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as
well as in chemical applications such as the catalytic transformation of organic substrates …
well as in chemical applications such as the catalytic transformation of organic substrates …
Combined experimental and theoretical study on the reductive cleavage of inert C–O bonds with silanes: ruling out a classical Ni (0)/Ni (II) catalytic couple and …
J Cornella, E Gómez-Bengoa… - Journal of the American …, 2013 - ACS Publications
A mechanistic and computational study on the reductive cleavage of C–OMe bonds
catalyzed by Ni (COD) 2/PCy3 with silanes as reducing agents is reported herein …
catalyzed by Ni (COD) 2/PCy3 with silanes as reducing agents is reported herein …
Fundamental studies and development of nickel-catalyzed trifluoromethylthiolation of aryl chlorides: active catalytic species and key roles of ligand and traceless …
A catalytic protocol to convert aryl and heteroaryl chlorides to the corresponding
trifluoromethyl sulfides is reported herein. It relies on a relatively inexpensive Ni (cod) 2/dppf …
trifluoromethyl sulfides is reported herein. It relies on a relatively inexpensive Ni (cod) 2/dppf …
Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials
Catalytic reactions that enable the formation of new bonds to carbon centres play a
pervasive role in the state-of-the-art synthesis of organic molecules and macromolecules. In …
pervasive role in the state-of-the-art synthesis of organic molecules and macromolecules. In …
Supported Electrophilic Organoruthenium Catalyst for the Hydrosilylation of Olefins
A series of supported electrophilic organoruthenium complexes has been synthesized via
surface organometallic chemistry (SOMC) techniques and applied to the selective …
surface organometallic chemistry (SOMC) techniques and applied to the selective …
Facile Si–H bond activation and hydrosilylation catalysis mediated by a nickel–borane complex
Metal–borane complexes are emerging as promising systems for study in the context of
bifunctional catalysis. Herein we describe diphosphineborane nickel complexes that activate …
bifunctional catalysis. Herein we describe diphosphineborane nickel complexes that activate …