Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis

C Pratley, S Fenner, JA Murphy - Chemical reviews, 2022 - ACS Publications
The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …

[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents

JD Bell, JA Murphy - Chemical Society Reviews, 2021 - pubs.rsc.org
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …

Atom transfer radical polymerization: a mechanistic perspective

F Lorandi, M Fantin… - Journal of the American …, 2022 - ACS Publications
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …

Photoinduced organocatalyzed atom transfer radical polymerization (O-ATRP): precision polymer synthesis using organic photoredox catalysis

DA Corbin, GM Miyake - Chemical reviews, 2021 - ACS Publications
The development of photoinduced organocatalyzed atom transfer radical polymerization (O-
ATRP) has received considerable attention since its introduction in 2014. Expanding on …

A toolbox approach to construct broadly applicable metal-free catalysts for photoredox chemistry: deliberate tuning of redox potentials and importance of halogens in …

E Speckmeier, TG Fischer, K Zeitler - Journal of the American …, 2018 - ACS Publications
The targeted choice of specific photocatalysts has been shown to play a critical role for the
successful realization of challenging photoredox catalytic transformations. Herein, we …

Photocatalytic systems: reactions, mechanism, and applications

F Mohamadpour, AM Amani - RSC advances, 2024 - pubs.rsc.org
The photocatalytic field revolves around the utilization of photon energy to initiate various
chemical reactions using non-adsorbing substrates, through processes such as single …

The advent and development of organophotoredox catalysis

T Bortolato, S Cuadros, G Simionato… - Chemical …, 2022 - pubs.rsc.org
In the last decade, photoredox catalysis has unlocked unprecedented reactivities in
synthetic organic chemistry. Seminal advancements in the field have involved the use of well …

Nickel‐catalyzed C‐heteroatom cross‐coupling reactions under mild conditions via facilitated reductive elimination

C Zhu, H Yue, J Jia, M Rueping - Angewandte Chemie, 2021 - Wiley Online Library
The formation of C‐heteroatom bonds represents an important type of bond‐forming
reaction in organic synthesis and often provides a fast and efficient access to privileged …

Visible-light-promoted C–S cross-coupling via intermolecular charge transfer

B Liu, CH Lim, GM Miyake - Journal of the American Chemical …, 2017 - ACS Publications
Disclosed is a mild, scalable, visible-light-promoted cross-coupling reaction between thiols
and aryl halides for the construction of C–S bonds in the absence of both transition metal …

A rational approach to organo‐photocatalysis: novel designs and structure‐property relationships

A Vega‐Peñaloza, J Mateos… - Angewandte Chemie …, 2021 - Wiley Online Library
Organic photocatalysts are emerging as viable and more sustainable tools than metal
complexes. Recently, the field of organo‐photocatalysis has experienced an explosion in …