Functional monolayers with coordinatively embedded metalloporphyrins

G Ashkenasy, G Kalyuzhny, J Libman… - Angewandte Chemie …, 1999 - Wiley Online Library
Perpendicularly oriented iron porphyrins are absorbed onto a gold surface when
interconnected long‐chain diimidazolyl groups coordinate axially to the metal center from …

[引用][C] Microscopic evidence of the metalation of a free‐base porphyrin monolayer with iron

F Buchner, V Schwald, K Comanici… - …, 2007 - Wiley Online Library
The self-assembly of molecular building blocks on crystalline surfaces into highly ordered
nanoarchitectures is an approach towards the creation of novel materials with outstanding …

Synthesis and properties of metalloporphyrin monolayers and stacked multilayers bound to an electrode via site specific axial ligation to a self-assembled monolayer

DA Offord, SB Sachs, MS Ennis… - Journal of the …, 1998 - ACS Publications
A general method has been developed for the immobilization of metalloporphyrins at a gold
electrode surface coated with a self-assembled monolayer (SAM). SAMs containing …

Direct synthesis of a metalloporphyrin complex on a surface

JM Gottfried, K Flechtner, A Kretschmann… - Journal of the …, 2006 - ACS Publications
We demonstrate that well-defined monolayers of a metal complex on a surface can be
prepared by direct vapor deposition of the metal atoms on monolayers of the ligand. In …

Nickel (II) tetraphenylporphyrin modified surfaces via electrografting of an aryldiazonium salt

AJ Gross, C Bucher, L Coche-Guerente… - Electrochemistry …, 2011 - Elsevier
We have prepared and isolated the monodiazonium salt of nickel (II) tetraphenylporphyrin
and grafted the corresponding complex to glassy carbon, pyrolysed photoresist film, gold …

Changes of the molecule–substrate interaction upon metal inclusion into a porphyrin

G Di Santo, C Sfiligoj… - … A European Journal, 2012 - Wiley Online Library
The self-assembly of molecular building blocks on crystalline surfaces into highly ordered
nanoarchitectures is an interesting approach towards the creation of novel materials with …

Self-assembly of metal free porphyrin layers at copper-electrolyte interfaces: Dependence on substrate symmetry

TH Phan, K Wandelt - Surface science, 2013 - Elsevier
Combined Cyclic Voltammetry (CV) and in-situ Electrochemical Scanning Tunneling
Microscopy (EC-STM) studies were employed to compare the self-assembly of redox-active …

Post-assembly insertion of metal ions into thiol-derivatized porphyrin monolayers on gold

N Nishimura, M Ooi, K Shimazu, H Fujii… - Journal of …, 1999 - Elsevier
The insertion of metal ions into thiol-derivatized free-base porphyrin monolayers pre-
assembled on gold has been conducted by refluxing the metal ion solution in which the …

Modular assembly and air-stable electrochemistry of ruthenium porphyrin monolayers

TA Eberspacher, JP Collman, CED Chidsey… - Langmuir, 2003 - ACS Publications
Two approaches are presented to the modular construction of alkanethiolate self-assembled
monolayers (SAMs) on gold surfaces selectively decorated with metalloporphyrins. In the …

[HTML][HTML] (Metallo) porphyrins for potential materials science applications

L Smykalla, C Mende, M Fronk, PF Siles… - Beilstein Journal of …, 2017 - beilstein-journals.org
The bottom-up approach to replace existing devices by molecular-based systems is a
subject that attracts permanently increasing interest. Molecular-based devices offer not only …