Differentiating Grotthuss proton conduction mechanisms by nuclear magnetic resonance spectroscopic analysis of frozen samples
T Ogawa, K Kamiguchi, T Tamaki, H Imai… - Analytical …, 2014 - ACS Publications
Available methods to analyze proton conduction mechanisms cannot distinguish between
two proton-conduction processes derived from the Grotthuss mechanism. The two …
two proton-conduction processes derived from the Grotthuss mechanism. The two …
Unraveling the complex hydrogen bonding of a dual-functionality proton conductor using ultrafast magic angle spinning NMR
JW Traer, E Montoneri, A Samoson, J Past… - Chemistry of …, 2006 - ACS Publications
Hydrogen bonding plays a critical role in proton-conducting polymers, as it provides the
network necessary for structural (Grotthus mechanism) diffusion. This network must be both …
network necessary for structural (Grotthus mechanism) diffusion. This network must be both …
Anhydrous proton-conducting polymeric electrolytes for fuel cells
SR Narayanan, SP Yen, L Liu… - The Journal of Physical …, 2006 - ACS Publications
The need to design proton-conducting electrolytes for fuel cells operating at temperatures of
120° C and above has prompted the investigation of various “water-free” polymeric …
120° C and above has prompted the investigation of various “water-free” polymeric …
Ion Conduction Mechanisms and Thermal Properties of Hydrated and Anhydrous Phosphoric Acids Studied with 1H, 2H, and 31P NMR
Y Aihara, A Sonai, M Hattori… - The Journal of Physical …, 2006 - ACS Publications
To understand the behaviors of phosphoric acids in fuel cells, the ion conduction
mechanisms of phosphoric acids in condensed states without free water and in a monomer …
mechanisms of phosphoric acids in condensed states without free water and in a monomer …
High-resolution solid-state NMR studies of poly (vinyl phosphonic acid) proton-conducting polymer: Molecular structure and proton dynamics
YJ Lee, B Bingöl, T Murakhtina… - The Journal of …, 2007 - ACS Publications
The structure and the local proton mobility of poly (vinyl phosphonic acid) were studied by
solid-state NMR under fast magic-angle spinning. At elevated temperatures, the signature of …
solid-state NMR under fast magic-angle spinning. At elevated temperatures, the signature of …
The proton conduction mechanism in a material consisting of packed acids
T Ogawa, T Aonuma, T Tamaki, H Ohashi… - Chemical …, 2014 - pubs.rsc.org
Proton conduction due to acid–acid interactions is an important topic in a variety of fields,
from materials science to biochemistry. We observed a distinctive proton conduction …
from materials science to biochemistry. We observed a distinctive proton conduction …
Uncovering Fast Solid-Acid Proton Conductors Based on Dynamics of Polyanion Groups and Proton Bonding Strength
Achieving high proton conductivity in inorganic solids is key for advancing many
electrochemical technologies, including low-energy nanoelectronics and energy-efficient …
electrochemical technologies, including low-energy nanoelectronics and energy-efficient …
Enhancement of 'dry'proton conductivity by self-assembled nanochannels in all-solid polyelectrolytes
Proton transport has been recognized as an essential process in many biological systems,
as well as electrochemical devices including fuel cells and redox flow batteries. In the …
as well as electrochemical devices including fuel cells and redox flow batteries. In the …
Proton transport for fuel cells
SM Haile, PN Pintauro - Journal of Materials Chemistry, 2010 - pubs.rsc.org
International efforts in fuel cell materials research have been largely driven by the need to
develop benign energy technologies. As is widely recognized, fuel cells have the potential to …
develop benign energy technologies. As is widely recognized, fuel cells have the potential to …
Molecular origin of enhanced proton conductivity in anhydrous ionic systems
Z Wojnarowska, KJ Paluch, E Shoifet… - Journal of the …, 2015 - ACS Publications
Ionic systems with enhanced proton conductivity are widely viewed as promising electrolytes
in fuel cells and batteries. Nevertheless, a major challenge toward their commercial …
in fuel cells and batteries. Nevertheless, a major challenge toward their commercial …