Differentiating Grotthuss proton conduction mechanisms by nuclear magnetic resonance spectroscopic analysis of frozen samples

T Ogawa, K Kamiguchi, T Tamaki, H Imai… - Analytical …, 2014 - ACS Publications
Available methods to analyze proton conduction mechanisms cannot distinguish between
two proton-conduction processes derived from the Grotthuss mechanism. The two …

Unraveling the complex hydrogen bonding of a dual-functionality proton conductor using ultrafast magic angle spinning NMR

JW Traer, E Montoneri, A Samoson, J Past… - Chemistry of …, 2006 - ACS Publications
Hydrogen bonding plays a critical role in proton-conducting polymers, as it provides the
network necessary for structural (Grotthus mechanism) diffusion. This network must be both …

Anhydrous proton-conducting polymeric electrolytes for fuel cells

SR Narayanan, SP Yen, L Liu… - The Journal of Physical …, 2006 - ACS Publications
The need to design proton-conducting electrolytes for fuel cells operating at temperatures of
120° C and above has prompted the investigation of various “water-free” polymeric …

Ion Conduction Mechanisms and Thermal Properties of Hydrated and Anhydrous Phosphoric Acids Studied with 1H, 2H, and 31P NMR

Y Aihara, A Sonai, M Hattori… - The Journal of Physical …, 2006 - ACS Publications
To understand the behaviors of phosphoric acids in fuel cells, the ion conduction
mechanisms of phosphoric acids in condensed states without free water and in a monomer …

High-resolution solid-state NMR studies of poly (vinyl phosphonic acid) proton-conducting polymer: Molecular structure and proton dynamics

YJ Lee, B Bingöl, T Murakhtina… - The Journal of …, 2007 - ACS Publications
The structure and the local proton mobility of poly (vinyl phosphonic acid) were studied by
solid-state NMR under fast magic-angle spinning. At elevated temperatures, the signature of …

The proton conduction mechanism in a material consisting of packed acids

T Ogawa, T Aonuma, T Tamaki, H Ohashi… - Chemical …, 2014 - pubs.rsc.org
Proton conduction due to acid–acid interactions is an important topic in a variety of fields,
from materials science to biochemistry. We observed a distinctive proton conduction …

Uncovering Fast Solid-Acid Proton Conductors Based on Dynamics of Polyanion Groups and Proton Bonding Strength

P Žguns, K Klyukin, LS Wang, G Xiong, J Li… - Energy & …, 2024 - pubs.rsc.org
Achieving high proton conductivity in inorganic solids is key for advancing many
electrochemical technologies, including low-energy nanoelectronics and energy-efficient …

Enhancement of 'dry'proton conductivity by self-assembled nanochannels in all-solid polyelectrolytes

AH Shah, J Li, H Yang, UA Rana… - Journal of Materials …, 2016 - pubs.rsc.org
Proton transport has been recognized as an essential process in many biological systems,
as well as electrochemical devices including fuel cells and redox flow batteries. In the …

Proton transport for fuel cells

SM Haile, PN Pintauro - Journal of Materials Chemistry, 2010 - pubs.rsc.org
International efforts in fuel cell materials research have been largely driven by the need to
develop benign energy technologies. As is widely recognized, fuel cells have the potential to …

Molecular origin of enhanced proton conductivity in anhydrous ionic systems

Z Wojnarowska, KJ Paluch, E Shoifet… - Journal of the …, 2015 - ACS Publications
Ionic systems with enhanced proton conductivity are widely viewed as promising electrolytes
in fuel cells and batteries. Nevertheless, a major challenge toward their commercial …