A rigid and healable polymer cross-linked by weak but abundant Zn (II)-carboxylate interactions
JC Lai, L Li, DP Wang, MH Zhang, SR Mo… - Nature …, 2018 - nature.com
Achieving a desirable combination of solid-like properties and fast self-healing is a great
challenge due to slow diffusion dynamics. In this work, we describe a design concept that …
challenge due to slow diffusion dynamics. In this work, we describe a design concept that …
Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers
There is often a trade-off between mechanical properties (modulus and toughness) and
dynamic self-healing. Here we report the design and synthesis of a polymer containing …
dynamic self-healing. Here we report the design and synthesis of a polymer containing …
A highly stretchable polymer that can be thermally healed at mild temperature
Combining stretchability and self‐healing properties in a man‐made material is a
challenging task. For an efficient self‐healing material, weaker dynamic or reversible bonds …
challenging task. For an efficient self‐healing material, weaker dynamic or reversible bonds …
Distinct mechanical and self-healing properties in two polydimethylsiloxane coordination polymers with fine-tuned bond strength
DP Wang, JC Lai, HY Lai, SR Mo, KY Zeng… - Inorganic …, 2018 - ACS Publications
Coordination bonds are effective for constructing highly efficient self-healing materials as
their strength is highly tunable. To design self-healing polymers with better performance, it is …
their strength is highly tunable. To design self-healing polymers with better performance, it is …
Facile fabrication of room-temperature self-healing, mechanically robust, highly stretchable, and tough polymers using dual dynamic cross-linked polymer complexes
H Guo, X Fang, L Zhang, J Sun - ACS applied materials & …, 2019 - ACS Publications
The development of polymeric materials with a combination of excellent mechanical
performance and room-temperature self-healing property is still a huge challenge. Here, we …
performance and room-temperature self-healing property is still a huge challenge. Here, we …
Self-healing multiphase polymers via dynamic metal–ligand interactions
D Mozhdehi, S Ayala, OR Cromwell… - Journal of the American …, 2014 - ACS Publications
A new self-healing multiphase polymer is developed in which a pervasive network of
dynamic metal–ligand (zinc–imidazole) interactions are programmed in the soft matrix of a …
dynamic metal–ligand (zinc–imidazole) interactions are programmed in the soft matrix of a …
Self‐healing polymers based on coordination bonds
Self‐healing ability is an important survival feature in nature, with which living beings can
spontaneously repair damage when wounded. Inspired by nature, people have designed …
spontaneously repair damage when wounded. Inspired by nature, people have designed …
Shape-memory and self-healing polymers based on dynamic covalent bonds and dynamic noncovalent interactions: synthesis, mechanism, and application
Z Li, R Yu, B Guo - ACS Applied Bio Materials, 2021 - ACS Publications
Shape-memory and self-healing polymers have been a hotspot of research in the field of
smart polymers in the past decade. Under external stimulation, shape-memory and self …
smart polymers in the past decade. Under external stimulation, shape-memory and self …
[PDF][PDF] A stiff and healable polymer based on dynamic‐covalent boroxine bonds
DOI: 10.1002/adma. 201602332 properties. Specifically, we use dynamic-covalent boroxine
bond to crosslink the poly (dimethylsiloxane)(PDMS) chain into 3D networks. The as …
bond to crosslink the poly (dimethylsiloxane)(PDMS) chain into 3D networks. The as …
Polymers with dynamic bonds: adaptive functional materials for a sustainable future
Polymeric materials play critical role in many current technologies. Among them, adaptive
polymeric materials with dynamic (reversible) bonds exhibit unique properties and provide …
polymeric materials with dynamic (reversible) bonds exhibit unique properties and provide …