Imprinting directionality into proton transfer reactions of an achiral molecule

J Kügel, M Leisegang, M Bode - ACS nano, 2018 - ACS Publications
Directionality is key for the functionality of molecular machines, which is often achieved by
built-in structural chiralities. Here, we present a scanning tunneling microscopy study of …

Reversible achiral-to-chiral switching of single Mn–phthalocyanine molecules by thermal hydrogenation and inelastic electron tunneling dehydrogenation

K Yang, L Liu, L Zhang, W Xiao, X Fei, H Chen, S Du… - ACS …, 2014 - ACS Publications
Induction of chirality in planar adsorbates by hydrogenation of phthalocyanine molecules on
a gold surface is demonstrated. This process merely lowers the molecular symmetry from 4 …

Bistable H2Pc Molecular Conductance Switch on Ag(100)

W Kamiński, G Antczak… - The Journal of Physical …, 2022 - ACS Publications
Scanning tunneling microscopy (STM) and density functional theory (DFT) were used to
study the tautomerization reaction of an H2Pc molecule adsorbed on a Ag (100) surface …

Current-driven supramolecular motor with in situ surface chiral directionality switching

P Mishra, JP Hill, S Vijayaraghavan, WV Rossom… - Nano …, 2015 - ACS Publications
Surface-supported molecular motors are nanomechanical devices of particular interest in
terms of future nanoscale applications. However, the molecular motors realized so far …

Chirality-specific unidirectional rotation of molecular motors on Cu (111)

M Schied, D Prezzi, D Liu, S Kowarik, PA Jacobson… - ACS …, 2023 - ACS Publications
Molecular motors have chemical properties that enable unidirectional motion, thus breaking
microscopic reversibility. They are well studied in solution, but much less is known regarding …

Supramolecular motors on graphite surface stabilized by charge states and hydrogen bonds

K Sun, JY Luo, X Zhang, ZJ Wu, Y Wang, HK Yuan… - ACS …, 2017 - ACS Publications
Molecular motors are nanoscale machines that convert external energies into controlled
mechanical movements. In supramolecular motors, the rotator and stator are held together …

Directing and Understanding the Translation of a Single Molecule Dipole

GJ Simpson, V García-López, AD Boese… - The Journal of …, 2023 - ACS Publications
Understanding the directed motion of a single molecule on surfaces is not only important in
the well-established field of heterogeneous catalysis but also for the design of artificial …

Steering organizational and conformational surface chirality by controlling molecular chemical functionality

C Bombis, S Weigelt, MM Knudsen, M Nørgaard… - ACS …, 2010 - ACS Publications
Molecular chirality on surfaces has been widely explored, both for intrinsically chiral
molecules and for prochiral molecules that become chiral upon adsorption due to the …

Remote single-molecule switching: Identification and nanoengineering of hot electron-induced tautomerization

J Kügel, M Leisegang, M Böhme, A Krönlein… - Nano Letters, 2017 - ACS Publications
Molecular electronics where single molecules perform basic functionalities of digital circuits
is a fascinating concept that one day may augment or even replace nowadays …

Direct observation of double hydrogen transfer via quantum tunneling in a single porphycene molecule on a Ag (110) surface

M Koch, M Pagan, M Persson… - Journal of the …, 2017 - ACS Publications
Quantum tunneling of hydrogen atoms (or protons) plays a crucial role in many chemical
and biological reactions. Although tunneling of a single particle has been examined …