Imprinting directionality into proton transfer reactions of an achiral molecule
Directionality is key for the functionality of molecular machines, which is often achieved by
built-in structural chiralities. Here, we present a scanning tunneling microscopy study of …
built-in structural chiralities. Here, we present a scanning tunneling microscopy study of …
Reversible achiral-to-chiral switching of single Mn–phthalocyanine molecules by thermal hydrogenation and inelastic electron tunneling dehydrogenation
Induction of chirality in planar adsorbates by hydrogenation of phthalocyanine molecules on
a gold surface is demonstrated. This process merely lowers the molecular symmetry from 4 …
a gold surface is demonstrated. This process merely lowers the molecular symmetry from 4 …
Bistable H2Pc Molecular Conductance Switch on Ag(100)
W Kamiński, G Antczak… - The Journal of Physical …, 2022 - ACS Publications
Scanning tunneling microscopy (STM) and density functional theory (DFT) were used to
study the tautomerization reaction of an H2Pc molecule adsorbed on a Ag (100) surface …
study the tautomerization reaction of an H2Pc molecule adsorbed on a Ag (100) surface …
Current-driven supramolecular motor with in situ surface chiral directionality switching
Surface-supported molecular motors are nanomechanical devices of particular interest in
terms of future nanoscale applications. However, the molecular motors realized so far …
terms of future nanoscale applications. However, the molecular motors realized so far …
Chirality-specific unidirectional rotation of molecular motors on Cu (111)
Molecular motors have chemical properties that enable unidirectional motion, thus breaking
microscopic reversibility. They are well studied in solution, but much less is known regarding …
microscopic reversibility. They are well studied in solution, but much less is known regarding …
Supramolecular motors on graphite surface stabilized by charge states and hydrogen bonds
K Sun, JY Luo, X Zhang, ZJ Wu, Y Wang, HK Yuan… - ACS …, 2017 - ACS Publications
Molecular motors are nanoscale machines that convert external energies into controlled
mechanical movements. In supramolecular motors, the rotator and stator are held together …
mechanical movements. In supramolecular motors, the rotator and stator are held together …
Directing and Understanding the Translation of a Single Molecule Dipole
GJ Simpson, V García-López, AD Boese… - The Journal of …, 2023 - ACS Publications
Understanding the directed motion of a single molecule on surfaces is not only important in
the well-established field of heterogeneous catalysis but also for the design of artificial …
the well-established field of heterogeneous catalysis but also for the design of artificial …
Steering organizational and conformational surface chirality by controlling molecular chemical functionality
C Bombis, S Weigelt, MM Knudsen, M Nørgaard… - ACS …, 2010 - ACS Publications
Molecular chirality on surfaces has been widely explored, both for intrinsically chiral
molecules and for prochiral molecules that become chiral upon adsorption due to the …
molecules and for prochiral molecules that become chiral upon adsorption due to the …
Remote single-molecule switching: Identification and nanoengineering of hot electron-induced tautomerization
J Kügel, M Leisegang, M Böhme, A Krönlein… - Nano Letters, 2017 - ACS Publications
Molecular electronics where single molecules perform basic functionalities of digital circuits
is a fascinating concept that one day may augment or even replace nowadays …
is a fascinating concept that one day may augment or even replace nowadays …
Direct observation of double hydrogen transfer via quantum tunneling in a single porphycene molecule on a Ag (110) surface
Quantum tunneling of hydrogen atoms (or protons) plays a crucial role in many chemical
and biological reactions. Although tunneling of a single particle has been examined …
and biological reactions. Although tunneling of a single particle has been examined …