A bis-acetonitrile two-coordinate copper (I) complex: synthesis and characterization of highly soluble B (C6F5) 4-Salts of [Cu (MeCN) 2]+ and [Cu (MeCN) 4]+
HC Liang, E Kim, CD Incarvito, AL Rheingold… - Inorganic …, 2002 - ACS Publications
Copper (I)− acetonitrile complexes are exceedingly useful starting materials for the synthesis
of copper (I) complexes with polydentate ligands. To extend the utility of such chemistry to …
of copper (I) complexes with polydentate ligands. To extend the utility of such chemistry to …
Cyano bridged dinuclear Cu (II) complexes
RJ Parker, L Spiccia, B Moubaraki, KS Murray… - Inorganica Chimica …, 2000 - Elsevier
The reaction of [CuL (OH2)] 2+, where L is one of the tripodal tetradentate ligands, tris (2-
pyridylmethyl) amine (tpa) or tris (2-aminoethyl) amine (tren), with cyanide ions, has yielded …
pyridylmethyl) amine (tpa) or tris (2-aminoethyl) amine (tren), with cyanide ions, has yielded …
Synthesis and characterization of a novel class of dicopper (I) bis (carboxylate)-bridged complexes
DD LeCloux, SJ Lippard - Inorganic Chemistry, 1997 - ACS Publications
The syntheses, spectroscopic properties, crystal and molecular structures, and bonding of
several dicopper (I) bis (carboxylate)-bridged complexes are described in which the bridging …
several dicopper (I) bis (carboxylate)-bridged complexes are described in which the bridging …
Crystal and molecular structures of several tetrakis (nitrile)copper(I) complexes
The crystal structures of several [Cu (RCN) 4] X salts (R= Me, X= SO 3 CF 3−; R= Ph, X= BF
4−, ClO 4−, and PF 6−) were determined using single crystal X-ray diffraction. All of the …
4−, ClO 4−, and PF 6−) were determined using single crystal X-ray diffraction. All of the …
Synthesis, molecular structure, and reactivity of dinuclear copper (II) complexes with carboxylate-rich coordination environments
RC Holz, JM Bradshaw, B Bennett - Inorganic chemistry, 1998 - ACS Publications
The dinucleating ligand N, N '-(2-hydroxy-5-methyl-1, 3-xylylene) bis (N-(carboxymethyl)
glycine)(CH3HXTA) has been used to synthesize the dinuclear Cu (II) bis (pyridine) complex …
glycine)(CH3HXTA) has been used to synthesize the dinuclear Cu (II) bis (pyridine) complex …
New, Multi‐Dimensional Cu(tn)‐[M(CN)6]n– Cyano‐Bridged, Bimetallic Coordination Materials (M = FeII, CoIII, CrIII and tn = 1,3‐Diaminopropane)
S Triki, J Sala‐Pala, F Thétiot, CJ Gómez‐García… - 2006 - Wiley Online Library
Reaction of the [FeIII (CN) 6] 3–anion with [CuII (tn)(H2O) n] 2+(tn= 1, 3‐diaminopropane)
affords the compounds [{CuII (tn)} 2 {FeII (CN) 6}]· KCl· 5H2O (1),[{CuII (tn)} 2 {FeII (CN) 6}] …
affords the compounds [{CuII (tn)} 2 {FeII (CN) 6}]· KCl· 5H2O (1),[{CuII (tn)} 2 {FeII (CN) 6}] …
Novel examples of high-dimensional mixed-valence copper cyanide complexes
D Kim, J Koo, CS Hong, S Oh, Y Do - Inorganic chemistry, 2005 - ACS Publications
The first examples of high-dimensional mixed-valence homometallic cyano-bridged copper
complexes were synthesized and characterized: net-structured [Cu (CN) 4 {Cu (cyclam)} 1.5] …
complexes were synthesized and characterized: net-structured [Cu (CN) 4 {Cu (cyclam)} 1.5] …
Fluoride as a terminal and bridging ligand for copper: isolation and x-ray crystallographic characterization of copper monomeric and dimeric complexes [CuII (TMPA) F …
RR Jacobson, Z Tyeklar, KD Karlin… - Inorganic chemistry, 1991 - ACS Publications
The copper (I) complex with tripodal tetradentate amine ligand TMPA,[Cu'(TMPA) CH3CN]
PF6 (1; TMPA= tris [(2-pyridyl) methyl] amine), reacts with dioxygen, resulting in breakdown …
PF6 (1; TMPA= tris [(2-pyridyl) methyl] amine), reacts with dioxygen, resulting in breakdown …
Nearly tetrahedral 1: 2 complexes of copper (I), copper (II), nickel (II), cobalt (II), and zinc (II) with 2, 2'-bis (2-imidazolyl) biphenyl
S Knapp, TR Keenan, X Zhang, R Fikar… - Journal of the …, 1987 - ACS Publications
We describe here several pseudotetrahedral complexeswhose tetrakis (imidazolyl) ligand
sets exhibit an unparalleled degree of geometric control. These chromophores are relevant …
sets exhibit an unparalleled degree of geometric control. These chromophores are relevant …
Homonuclear copper (II) complexes with multidentate amino alcohol ligands. Synthesis and characterization of a hexanuclear copper compound with a propeller …
A new hexanuclear copper (II) complex with the formula Cun6 (bdmap) 3Cl6 (0)(0H)(1;
bdmap= 1, 3-bis-(dimethylamino)-2-propanolato) has been synthesized andcharacterized …
bdmap= 1, 3-bis-(dimethylamino)-2-propanolato) has been synthesized andcharacterized …