Amide bond formation using an air-stable source of AlMe3
A Novak, LD Humphreys, MD Walker, S Woodward - Tetrahedron letters, 2006 - Elsevier
Synthesis of amides from coupling esters with a range of primary amines can be
conveniently achieved in moderate to excellent yields (69–99%) using an air-stable adduct …
conveniently achieved in moderate to excellent yields (69–99%) using an air-stable adduct …
AlMe3-Promoted Formation of Amides from Acids and Amines
J Li, K Subramaniam, D Smith, JX Qiao, JJ Li… - Organic …, 2012 - ACS Publications
In the presence of AlMe3, amines can be directly coupled with acids through
dimethylaluminum amide intermediates to form the corresponding amides. A wide range of …
dimethylaluminum amide intermediates to form the corresponding amides. A wide range of …
m-Terphenyl-Substituted Amidinates: Useful Ligands in the Preparation of Robust Aluminum Alkyls
D Abeysekera, KN Robertson, TS Cameron… - …, 2001 - ACS Publications
The syntheses of m-terphenyl-substituted amidines and their corresponding
dialkylaluminum amidinate complexes are reported. The amidines are prepared in a one-pot …
dialkylaluminum amidinate complexes are reported. The amidines are prepared in a one-pot …
Reactions of N-Monosubstituted Amidines with AlMe3 and AlMeCl2: Formation of Fused Triazaalane Heterocycles
K Maheswari, ND Reddy - Organometallics, 2012 - ACS Publications
Reactions of N-monosubstituted amidines of the formula HN C (R)–NH (R′)(R= Ph, 4-tert-
butylphenyl, Me; R′= 2, 6-diisopropylphenyl, Ph) with AlMe3 and AlMeCl2 are reported. All …
butylphenyl, Me; R′= 2, 6-diisopropylphenyl, Ph) with AlMe3 and AlMeCl2 are reported. All …
[引用][C] One-Pot Neat Reactions of Carboxylic Esters and Alkylenediamines for Efficient Preparation of N-Acylalkylenediamines
WC Chou, CW Tan, SF Chen, H Ku - The Journal of Organic …, 1998 - ACS Publications
The amide unit is one of the most widely occurring functional groups. It is present as a key
feature in many important natural products and man-made compounds. 1 For example …
feature in many important natural products and man-made compounds. 1 For example …
DIBAL–H–H2NR and DIBAL–H–HNR1R2· HCl complexes for efficient conversion of lactones and esters to amides
PQ Huang, X Zheng, XM Deng - Tetrahedron Letters, 2001 - Elsevier
The reaction of a lactone or an ester with organoaluminum species generated from DIBAL–
H–H2NR or DIBAL–H–HNR1R2· HCl complexes provided efficient methods for preparation …
H–H2NR or DIBAL–H–HNR1R2· HCl complexes provided efficient methods for preparation …
[引用][C] Conversion of Esters to Amides with Dimethylaluminum Amides: N,N‐Dimethylcyclohexanecarboxamide
MF Lipton, A Basha, SM Weinreb - Organic Syntheses, 2003 - Wiley Online Library
Conversion of esters to amides with dimethylaluminum amides: N, N‐
dimethylcyclohexanecarboxamide reactant: 7.10 g.(0.0500 mole) of methyl …
dimethylcyclohexanecarboxamide reactant: 7.10 g.(0.0500 mole) of methyl …
An alternative procedure for the aluminum-mediated conversion of esters to amides
JI Levin, E Turos, SM Weinreb - Synthetic Communications, 1982 - Taylor & Francis
An Alternative Procedure for the Aluminum-Mediated Conversion of Esters to Amides Page 1
SYNTHETIC COMMUNICATIONS, 12(13), 989-993 (1982) AN ALTERNATIVE PROCEDURE …
SYNTHETIC COMMUNICATIONS, 12(13), 989-993 (1982) AN ALTERNATIVE PROCEDURE …
Synthesis of amide derivatives for electron deficient amines and functionalized carboxylic acids using EDC and DMAP and a catalytic amount of HOBt as the coupling …
AK Ghosh, D Shahabi - Tetrahedron letters, 2021 - Elsevier
A convenient protocol for amide bond formation for electron deficient amines and carboxylic
acids is described. Amide coupling of aniline derivatives has been investigated with a …
acids is described. Amide coupling of aniline derivatives has been investigated with a …
Reaction of trimethylaluminium with a tridentate open-chain amine. Synthesis and molecular structure of [Al (CH3)] 2 [C12H28N6][Al (CH3) 2] 2
GH Robinson, F Moise, WT Pennington, SA Sangokoya - Polyhedron, 1989 - Elsevier
Abstract Reaction of 3, 3′-iminobispropylamine with trimethylaluminium affords the
crystalline complex [Al (CH 3)] 2 [C 12 H 28 N 6][Al (CH 3) 2] 2. The title compound …
crystalline complex [Al (CH 3)] 2 [C 12 H 28 N 6][Al (CH 3) 2] 2. The title compound …