Designing a molecular magnetic button based on 4d and 5d transition-metal phthalocyanines

P Ferriani, S Heinze, V Bellini - Scientific reports, 2017 - nature.com
… , we have devised a functional molecule exhibiting different magnetic states upon structural
… M-Phthalocyanine (MPc), where M is a transition-metal ion belonging to the 4d and 5d series…

Smart ligands for efficient 3d-, 4d-and 5d-metal single-molecule magnets and single-ion magnets

PS Perlepe, D Maniaki, E Pilichos, E Katsoulakou… - Inorganics, 2020 - mdpi.com
… used to design and synthesize novel crystalline molecule-based materials exhibiting useful
molecular magnetic materials [19,20]. The focus of this review is on transition-metal SMMs …

Magnetism and magnetic anisotropy of transition metal-phthalocyanine molecules

J Hu, R Wu - arXiv preprint arXiv:1402.0278, 2014 - arxiv.org
… FePc molecules were found to switch their magnetic … potential candidates from 4d or 5d TM-Pc
molecules that have large spin… efforts for the design of innovative magnetic molecules and …

Giant magnetocrystalline anisotropy of 5d transition metal-based phthalocyanine sheet

J Zhou, Q Wang, Q Sun, Y Kawazoe… - Physical Chemistry …, 2015 - pubs.rsc.org
molecule magnets based on 3d metals is small and in typical … Our interest in this paper is
to design poly-TMPc based … Compared with 3d/4d TM atoms, heavier 5d elements usually …

Controlling the magnetism of adsorbed metal–organic molecules

W Kuch, M Bernien - Journal of Physics: Condensed Matter, 2016 - iopscience.iop.org
transition metal porphyrin and phthalocyanine molecules … shell of Mn 2+ and the Eu 5d
electrons is held responsible for the … If the creativity in designing new molecules with interesting …

Single ion magnets from 3d to 5f: developments and strategies

M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
… SIMs, including 3d and 5d transition metal ions, 4f lanthanide ions, … ), was reported, strategies
of ligand field design have … 2 Tb] (Pc=dianion of phthalocyanine) was reported to exhibit a …

Molecular chemistry approaches for tuning the properties of two-dimensional transition metal dichalcogenides

S Bertolazzi, M Gobbi, Y Zhao, C Backes… - Chemical Society …, 2018 - pubs.rsc.org
… 6 Doping of TMDs by metal phthalocyanines. (a) Schematic representation of a TMD sheet
… to optimize the nanoscale molecular assembly but also to assist chemists in the design of …

Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
… mono- and multinuclear molecular complexes, spanning transition metal-, lanthanide-, and
… enormous success in the rational design of molecule-based magnetic materials, they will not …

High-throughput screening of transition-metal-atom-embedded parallel tetracyanoethylene 2D networks as single-atom electrocatalysts for ammonia synthesis and its …

D Deng, B Song, C Li, LM Yang - The Journal of Physical …, 2022 - ACS Publications
… This work will shed some light on the rational design of … ], which consists of TM (3d/4d/5d)
as active sites and TCNEs as … From Figure 1b, we can see that all of the TCNE molecules are …

Lanthanide coordination chemistry: from old concepts to coordination polymers

JCG Bünzli - Journal of Coordination Chemistry, 2014 - Taylor & Francis
… Long considered as minor actors in transition metal chemistry, they … -based ligands, porphyrins,
phthalocyanines, and Schiff base ligands are interesting building blocks for the design of …