Harnessing enzymes which possess several catalytic activities is a topic where intense
research has been carried out, mainly coupled with the development of cascade reactions …

Artificial enzymes based on the modification of a protein structure for the creation of new
active catalytic sites have experienced a great boom in recent years. Multidisciplinary …

The fact that many enzymes have broad substrate specificity has been a property of
fundamental importance for the widespread applications of enzymes in synthetic chemistry …

Artificial metalloenzymes, with their high selectivity and specificity combined with a wide
scope of reactivity and substrates, constitute an original approach for catalyst development …

Biocatalysis has been attracting increasing interest in recent years. Nevertheless, most
studies concerning biocatalysis have been carried out using single enzymes (soluble or …

Enzymes are highly evolved catalysts that perform their tasks with high efficiency. 1 Hence,
they may constitute a very attractive reference in the development of a synthetic catalyst. The …

The design of artificial enzymes has emerged as a promising tool for the generation of
potent biocatalysts able to promote new-to-nature reactions with improved catalytic …

By combining homogeneous with enzymatic catalysis, artificial metalloenzymes offer new
perspectives for conferring unnatural activities to biomolecules. The article reassembles the …

The immobilization of multi-enzyme systems on advanced materials is an emerging
technology inspired by the spatial localization found in Nature. These systems harness the …

Enzymes are attractive catalysts because of their promiscuity and their ability to perform
highly regio‐, chemo‐and stereoselective transformations. Enzyme promiscuity allows …