The development of homogeneous catalysis is enabled by the availability of a rich toolkit of
kinetics experiments, such as the Hg-drop test, that differentiate catalytic activity at ligand …

Metal–organic frameworks (MOFs) are a class of nanoporous materials with highly tunable
structures in terms of both chemical composition and topology. Due to their tunable nature …

Metal–organic frameworks (MOFs) are becoming increasingly popular as heterogenous
support matrices for molecular catalysts. Given that reactants, or potentially holes/electrons …

Few-atom cobalt-oxide clusters, when dispersed on a Zr-based metal–organic framework
(MOF) NU-1000, have been shown to be active for the oxidative dehydrogenation (ODH) of …

Achieving active site engineering at the atomic level poses a significant challenge in the
design and optimization of catalysts for energy‐efficient catalytic processes, especially for a …

Single-site heterogeneous catalysts (SSHCs) play important roles in fundamental science
and technology, owing to the molecular level control of structure–support interactions that is …

Partial substitution of ZnII by MnII in Zn4O (terephthalate) 3 (MOF-5) leads to a distorted all-
oxygen ligand field supporting a single MnII site, whose structure was confirmed by Mn K …

Converting light hydrocarbons such as methane, ethane, propane, and cyclohexane into
value‐added chemicals and fuel products by means of direct C− H functionalization is an …

Conspectus Comprising periodically repeating inorganic nodes and organic linkers, metal–
organic frameworks (MOFs) represent a novel class of porous molecular solids with well …

The unlimited combination of building units, tunable structures, and facilitation of tailoring
active sites endows metal-organic frameworks (MOFs) with high activity as heterogeneous …